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Infiltration of Biopolymers into Mesoporous Particles
Developing Mathematical Models for Complex Polymeric Systems

​ Developing Mathematical Models
for Complex Polymeric Systems

[ Coarse-grained Model of Bottlebrushes ]

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  • Coarse-grained molecular simulation of bottlebrush polymer

  • Investigating the effects of grafting density on the stiffness of polymer

  • Predicting conformation and phase behavior of bottlebrush block copolymer system

[ Morphological Diversity in Graft-Linear Block Copolymer(BCPs) ]

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  • Coarse-grained molecular simulation of comb polymer

  • Investigating the effects of grafting density on phase transitions

  • Predicting conformation and phase behavior of comb polymer system

[ Mesoscale Simulation Model for Solution Assembly ]

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  • Generic Framework of Mesoscale Simulations for Solution Self-Assembly of Polymers

  • Investigating the relationship between the model parameters and experimentally measurable quantities (e.g., single-chain conformation, chain density, interfacial and surface tensions)

  • Polymer solution assembly over a wide range of concentrations and solvent qualities

  • Predicting structure and shape evolution in emulsified BCP droplets

[ Solution Assembly of Amphiphilic Grafting Polymer ]

  • Developed a coarse-grained model-based simulator for grafting polymer self-assembly with diverse chain architectures.

  • Explored effects of chain architecture on amphiphilic grafting polymers in solutions, considering grafting density, distribution of grafting points, and polymer concentration.

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[ Modeling of Extreme Ultraviolet (EUV)
Photoresist & Patterning Process ]

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  • Development of coarse-grained molecular simulation reflecting both chain conformation and stochastic terms (e.g. photon shot noise, acid diffusion) for EUV patterning process.

  • Investigation on the effect of photon distribution, material conformation, acid diffusion, and initial chain alignment on the final roughness of EUV resist.

[ High-resolution Patterning Combined with
EUV and DSA (Directed Self-Assembly) ]

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  • Exploring the application of Directed Self-Assembly (DSA) on EUV Lithography Patterns for Line Patterns or Cylindrical Patterns and defect removal through simulation and modeling

  • Understanding the relationship between the chemical structure and self-assembly characteristics of polymers

  • Exploring new materials and mechanisms that can create optimal structures when combined with EUV lithography

[ Dielectric Spectroscopy of Low Permittivity Polymers ]

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Calculation of dielectric properties

  • Dielectric constant estimation for polymers in melt using Molecular Dynamic simulations

  • Exploring the effect of different functional groups in the complex permittivity as function of frequency

  • Evaluate the suitability of additives that maintain or improve the dielectric properties of the studied polymers

[ Infiltration of Biopolymers into Mesoporous Particles ]

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  • Developing a coarse-grained simulation model for porous particles and polymer

  • Understanding structural parameters effect on cohesion strength

[ Solvent Vapor annealing ]

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  • Molecular dynamic simulation of our virial model to observe the dynamic sphere splitting phenomenon behind pattern multiplication during Solvent Vapor Annealing

  • By mapping the local energies, it is found that local interfacial energies are the main driving force of the splitting rather than chain stretching/compressing

Coarse-grained Model of Bottlebrushes
Mesoscale Simulation Model for Solution Assembly
Solution Assembly of Amphiphilic Comb Polymer
High-resolution Patterning Combined with EUV and DSA (Directed Self-Assembly)
Modeling of Extreme Ultraviolet (EUV) Photoresist & Patterning Process 
Dielectric Spectroscopy of Low Permittivity Polymers
Morphological Diversity in Graft-Linear Block Copolymer(BCPs)
Solvent Vapor Annealing
​Materials/Systems Design through Data Science and Machine Learning Techniques

Materials/Systems Design through Data Science
and Machine Learning Techniques

[ Defect Detection and Classification ]

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  • Detection and classification of defects in directed self-assembly of block copolymers using machine learning (YOLOv3)

  • Augmenting simulated data to limited experimental data to enhance the network training : testing efficiency for data mixing or transfer learning 

  • Evaluating  data quality for network performance

[ Polymer Property Prediction and Inverse Design ]

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  • Applying deep learning to polymer systems

  • Classification: Identification of defects in directed self-assembly of block copolymers.

  • Estimation: Prediction of polymer properties

  • Inverse design: Generating a new polymer structure using deep learning

[ Battery State-of-Health(SOH) Prediction ]

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  • Applying deep learning to battery systems

  • Estimation: Prediction of state of health of battery using Electrochemical Impedance Spectroscopy data

  • Feature reduction : SHAP analysis for investigating the feature impact on SOH, PCA for simplifying complexity of the data

[ Molecular Dynamic Simulations Combined with Machine Learning  ]

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  • Precise measurement of Glass Transition Temperature (Tg) achieved by clustering the Radius of Gyration (Rg) across multiple timeframes and temperatures.

  • Observing the Tg depiction of polymer free-standing thins films as a function of thickness and further insights into the different Tg of interface and center region of the film using clustering method

Polymer Property Prediction and Inverse Design
Defect Detection and Classification
Battery State-of-Health(SOH) Prediction
Molecular Dynamic Simulations Combined with Machine Learning
Non-simple Boundary and Its Effects on Self-assembly

Non-simple Boundary and
Its Effects on Self-assembly

[ Emulsified BCP droplets ]

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  • Predicting structure and shape evolution in emulsified BCP droplets

  • Investigating the effects of surface energy difference on the final morphology  

[ Boundary Directed Epitaxy ]

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  • Development of efficient simulation approaches using Monte Carlo and Molecular Dynamics frameworks to investigate complicated geometric surface effects.

  • Validation of these approaches by quantifying the importance of non-flat free top surface in the experimental system of self-assembly of tri-block copolymer on graphene nano-ribbons.

  • Further studies to understand the role of 3D bottom substrates in the mechanism of defect annihilation for lamellae-forming block copolymer systems.

[ Multicomponent Polymer brushes ]

  • Morphologies of block copolymer brushes and mixed polymer brushes under various conditions

  • Investigation on the effect of system parameters (e.g. molar composition, grafting density, segregation strength, surface interactions, solvent quality) on phase behavior of brushes

[ Phase Evolution of Block Copolymer on Preferential Substrate ]

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  • Morphology formation and phase evolution of block copolymer films depending on interfacial wetting condition

  • Effect of irreversibly adsorbed layer on phase behavior of BCP

Emulsified Polymer Droplet
Boundary-directed Epitaxy
Multi-component Polymer Brushes
Phase Evolution of Block Copolymer on Preferential Substrate
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